The beneficiation processing of molybdenum ore is mainly performed by flotation, and the recovered molybdenum mineral is molybdenite(MoS2). Sometimes in order to improve the quality of molybdenum concentrate and remove impurities, the concentrated molybdenite would be subjected to a further step of chemical beneficiation processing.
Introduction of molybdenite
Molybedenite’s chemical composition with a high molybdenum content, it is the most important mineral raw material for extracting molybdenum. Also, molybdenite is the most widely distributed molybdenum mineral, mainly produced in high and medium temperature hydrothermal fluids and skarn deposits. It is easy to weather into MoO3 on the surface ground. Claymax and Yulard-Henderson in Colorado, USA are world-renowned molybdenite deposits.
|Crystal structure||Body-centered cubic (BCC)|
|Lattice constant||a = 3.1470 Å|
|Coefficient of thermal expansion||4.8 x 10-6 / K at 25°C|
|Thermal conductivity||138 W/m K at 20°C|
Table data are from International Molybdenum Association
Molybdenite crystals are hexagonal layered or sandwich-like structures, which are formed by the S-Mo-S structure and S-Mo bond, along with the Van der Waals force between the two layers. The Mo-S bonds are strong, but the interaction between the sulfur atoms at the top and bottom of separate sandwich-like tri-layers is weak. Therefore, molybdenite is easily produced in the form of flakes or plates along the interlayer of the structure, which is the reason why chalcocite has good natural floatability. Practice has proved that: under suitable grinding fineness, the dissociation of molybdenite crystals occurs between the S-Mo-S layers, and the hydrophilic S-Mo surface only accounts for a small proportion.
Molybdenite flotation processing flow
During overgrinding, the proportion of S-Mo surface increases and the floatability decreases. Although a certain amount of polar collectors such as xanthates are added at this time, it is beneficial to the recovery of molybdenite, but the new sludge produced by overgrinding will affect the flotation effect. Therefore, the separation of molybdenite should avoid and prevent over-grinding. In the production, it is necessary to adopt segmented grinding and multi-stage separation processes to gradually achieve monomer dissociation and ensure a high recovery rate of molybdenum concentrate. The crushing of molybdenum ore generally uses a three-stage one-closed-circuit process, and the final product size is 12-15 mm.
Ball mill for ore grinding processing
Usually use the ball mill or rod mill-ball in the ore milling process. But there are also some processing flows adapted to use a semi-self-grinding process. Flotation adopts priority flotation method. Rough separation produces coarse molybdenum concentrate, and rough sweeping tailings recover associated minerals or discard. The coarse molybdenum concentrate is reground in two or three stages, and the final molybdenum concentrate is obtained by four or five times of selection.
The flotation reagent of molybdenum ore uses non-polar oils as collectors, while adding foaming agents. The United States and Canada use the surfactant Syntex as an oil emulsifier. According to the nature of the ore, lime is used as a regulator, water glass is used as a gangue inhibitor, and sometimes cyanide or sulfide is added to inhibit other heavy metal minerals.
How to improve concentration quality
In order to ensure the quality of molybdenum concentrate, the heavy metal minerals such as copper, lead and iron contained in molybdenum concentrate and calcium oxide and carbon minerals need to be further separated: generally use sodium sulfide or sodium hydrosulfide, cyanide or ferricyanide Make copper and iron; use dichromate or Nokes to suppress lead. If inhibitors are used, the impurity content is not up to the quality standard, and chemical beneficiation treatment is needed: secondary copper sulfide is leached with cyanide; chalcopyrite is leached with ferric chloride solution; galena is with hydrochloric acid and trichloride The iron leaching solution can reach the standard content.
Calcium oxide-containing gangue is easy to mud. Therefore, over-grinding of ore containing this kind of gangue should not be avoided. In production, water glass, sodium hexametaphosphate or organic glue is often added as gangue inhibitor or dispersant; activated carbon and CMC (carboxymethyl cellulose) can also be used to inhibit carbonate gangue. Finally, it can be leached with hydrochloric acid or hydrochloric acid plus ferric chloride solution.
In the separation of carbonaceous minerals, it is first necessary to find out whether the carbonaceous is graphite, pitch, or coal. The floatability of these carbonaceous minerals is similar to that of molybdenite, but the density is relatively small, and generally can be removed by gravity separation; use sodium hexametaphosphate and CMC to inhibit carbon floating molybdenum; or add ferric chloride, water glass And sodium hexametaphosphate is also effective in inhibiting carbon quality; roasting to remove organic carbon is also one of the methods. It should be pointed out that the separation methods of all these carbonaceous minerals are not yet satisfactory, and it is still an unsolved problem.
Factors that affect the grade of the concentrate
The high content of SiO2 (silicon dioxide) in gangue is often the reason that affects the grade of molybdenum concentrate. It has been verified that the content of SiO2 decreases as the grade of molybdenum concentrate increases, and the two tend to consume each other. As long as the molybdenum mineral reaches the monomer dissociation fineness, the SiO2 content can generally be reduced below the standard. Adding activated carbon to adsorb the oil on the surface of molybdenum, and adding CMC to inhibit silicate gangue, the SiO2 content can also be reduced to below the standard.